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2.00 mol of an ideal gas undergoes isothermal expansion along three different paths: (1). reversible expansion from Pinitial=25.0 bar and Vinitial=4.50L to Pfinal=4.50 bar, (2) a single step irreversible expansion against a constant external pressure of 4.50 bar and (3) a two step irreversible expansion consisting initially of an expansion against a constant external pressure of 11.0 bar until P=Pexternal, followed by an expansion against a constant external pressure of 4.50 bar until P=Pexternal. Calculate the work for each of these processes. For which of the irreversible processes is the magnitude of the work greater?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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