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If you have three pyruvate molecules each labeled with 14C at different positions (one is labeled at the carboxyl, one at the carbonyl, and one at the methyl), feed them sequentially to pyruvate dehydrogenase and the citric acid cycle, starting with the one labeled at the carboxyl take that to oxaloacetate, then follow with the one labeled at the carbonyl all the way to oxaloacetate keeping track of both 14C labels, and lastly the one labeled at the methyl..keeping track of all 3 14C labels. In the end, in what molecule(s) and at what position would the label reside when finished? If liberated as carbon dioxide, what step? Show work (on additional sheet(s) of paper, if necessary).
A cube of a silver-colored metal with a volume of 64 cm3 has a mass of 672 g. The density of pure silver is 10.5 g/cm3. Is the metal pure silver?
What concentrations of [K2HPO4] and [KH2PO4] will you need to make the total concentration 0.50 M? 3.) How many moles of K2HPO4 and KH2PO4 will you need? 4.) What mass of K2HPO4 and KH2PO4 will you need?
An enzyme-catalyzed reaction produces a product that has a maximum absorbance at 412 nm. The extinction coefficient is 4000 M^-1 cm^-1. A 10-to-1 dilution of the enzyme is made and 20 microliter of the dilution are put into a cuvette with 80 micro..
What is the freezing point of an aqueous 2.65 m calcium chloride (CaCl2) solution? The freezing point of pure water is 0.0ºC and Kf of pure water is -1.86ºC/m.
If 37.0 grams of hydrogen sulfide gas (H2S; MM = 34.08 g/mol) react with 37.1 grams of oxygen gas (O2, MM = 32.00 g/mol), what is the mass of sulfur dioxide (SO2, MM = 64.06 g/mol) gas produced?
what is heat of vaporization of a liquid that has a vapor pressure of 606 torr at 84 degrees celsius and a boiling point of 96.3 degrees celsius at 1 atm?
Calculate the molarity of of each ion present in the solution. Please walk me through the steps I'm trying to help my daughter with her chem. homework and I don't know any chem.
Barium sulfate, BaSO4, is made by the following reaction: Ba(NO3)2(aq) + Na2SO4(aq) à BaSO4(s) + 2NaNO3(aq).
Consider a glass of 298 mL of water at 30°C. Calculate the mass of ice at -15°C that must be added to cool the water to 10°C after thermal equilibrium is achieved.
The iron content of hemoglobin can be determined by converting the iron to Fe2+ and titrating using MnO4 -. A 5.0 g sample of hemoglobin requires 21.6 mL of 0.00310 M potassium permanganate. What is the percent of iron in the hemoglobin sample?
A sample of water 53 g with a temperature of thirty six degree celsius is combined to 250 grams of H 2 O at 91 degree Celsius in an insulated container. Determine the final temperature after thermal equilibrium is reached?
What is the magnetic field strength of the NMR system in Tesla? Show all equations and explain. c) Are the resonances of A and B well enough resolved to be able to measure the relative concentrations by NMR? Explain reasoning.
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