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Living organisms use energy from the metabolism of food to create an energy-rich molecule called adenosine triphosphate (ATP). The ATP then acts as an energy source for a variety of reactions that the living organism must carry out to survive. ATP provides energy through its hydrolysis, which can be symbolized as follows:
uploaded image\Delta G_{{\rm{rxn}}}^\circ = -30.5 {\rm{ kJ}}
where ADP represents adenosine diphosphate and Pi represents an inorganic phosphate group (such as HPO_4 ^2-).
a)Calculate the equilibrium constant, K, for the above reaction at 298 {\rm K}.
b)The free energy obtained from the oxidation (reaction with oxygen) of glucose {\rm{(C}}_6 {\rm{H}}_{12} {\rm{O}}_6 ) to form carbon dioxide and water can be used to re-form {\rm ATP} by driving the above reaction in reverse. Calculate the standard free energy change for the oxidation of glucose.
c)Estimate the maximum number of moles of {\rm ATP} that can be formed by the oxidation of one mole of glucose.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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