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1.) How would you distinguish experimentally between an amphourous, a crystalline and a crosslinked polymer?
2.) Consider 3 samples of polyisobutylene. All molecules in sample A have a molecular weight 30,000g/mol; all those in B have a molecular weight of 70,000 g/mol; and those in C have a molecular weight of 100,000 g/mol. If 10g of A are mixed with 5g of B and 1g of C, Calculate average Mn and average Mw.
A compound, C7H12O4, has an IR spectrum showing a peak at 1735 cm-1. Its 1H NMR spectrum has peaks at delta 1.3 (6 H, triplet), 3.4 (2 H, singlet), and 4.2 (4 H, quartet). Draw its structure
Water, sodium hydroxide, and 1,6-hexanediamine are all potential nucleophiles. Yet, only 1,6-hexanediamine reacts with the adipoyl chloride. Offer an explanation as to why.
Some watch dials are coated with a phosphor, like ZnS , and a polymer in which some of the first H atoms have been replaced by third H atoms, tritium.
In the nitration of methyl benzoate, why do you wash the crystals with water followed by an ice-cold methanol washing? What is the purpose of pouring the reaction mixture over ice?
What mass of HCl gas must be added to 1.00 L of a buffer solution that contains [acetic acid] = 2.0 M and [acetate] = 1.0 M in order to produce a solution
Ionizable protons are in rapid equilibrium and so you can think of an amino acid having a relative charge between 0 and 1. Plot the relative charge of glutamate as a function of pH
What is the balanced equation for the synthesis of Acetylsalic acid (Aspirin) from Methyl salicylate?
Calculate the molar concentration of H3PO4 in this solution: Calculate the number of grams of this solution required to hold 87.5 g H3PO4:
a solution is made up by dissolving 73 g of glucose in 966 g of water. calculate the activity coefficient of glucose in
A solution is prepared by dissolving 13.4 g ammonium sulfate in enough water to make 100.0 mL of stock solution. A 12.00 mL sample of this stock solution is added to 57.00 mL of water. Calculate the concentration of ammonium ions and sulfate ions ..
below, 8.34 atm each of H2 and Br2 were placed into a 1.00 L flask and allowed to react: H2(g) + Br2(g) 2 HBr(g) Given that Kc = 86.7, calculate the equilibrium pressure of Br2.
If 7.63 of an unknown gas occupies 79.1mL at 25.02 degrees celcius and 7.55 atm of pressure, what is the molar mass of the gas? R=0.0821
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