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CH3316 Homogeneous Catalysis
Question 1: Construct catalytic cycles using fundamental organometallic reaction steps.
Question 2: Understand how d-block metals can be used to effect catalytic transformations.
Question 3: Understand how empirical data can be used to construct catalytic cycles or identify key steps in the cycles
Question 4: Propose mechanistic details by interpreting experimental data.
Question 5: Explain chemo- regio- and stereo-selectivity in terms of a catalytic mechanism.
Question 6: Understand how knowledge of mechanism can lead to process optimisation.
Question 7: Understand the importance of the support ligand(s) and how they can be designed for function.
Determine the activation energy (EA) for a reaction which quadruples on a temperature increase from 30oC to 60oC.
How much MgSO4 anhydrous do you need to make buffer
if your air conditioner is more than several years old it may use the chloroflurocarbon ccl2f2 as the heat transfer
The normal boiling point of the liquid is 425 K. Liquid, X, and Y are all in equilibrium at 342 K and 1800 bar. Tc = 571K, Pc= 46 bar
solid sodium sulfate reacts with solid carbon to form solid sodium sulfide and carbon monoxide. if 15 grams of sodium
On one column two peaks have resolution 0.9 (not completely resolved). calculate resolution for the same components on twice longer column.
Calculate Qsp for calcium fluoride (Ksp=3.9x10^-11) when 195.0 mL of a 0.00780 M solution of Ca(NO3)2 is added to 175.0 mL of a 0.00740 M solution of KF
Refer to Part 1. For waste disposal, the gas is moved to a 22.0 L container, and cooled to a temperature at which the gas pressure is 8.60 x 103 mm Hg. Calculate the final temperature of the gas in absolute Kelvin.
A doctor has ordered that a patient be given 11 g of glucose, which is available in a concentration of 55.00 g glucose/1000.0 mL
A galvanic cell consists of an Ag(s)/Ag(aq) half cell and a Zn(s)/Zn2+ half-cell connected by a salt bridge. Write the two half cell reactions the standard reduction potentials too
The shielding of electrons gives rise to an effective nuclear charge,Zeff , which explains why boron is larger than oxygen. Estimate the approximate Zeff felt by a valence electron of boron and oxygen, respectively
A sample of O2 gas is placed in a sealed 1.00 L flask and pressure is measured as temperature is changed. The data are plotted and the slope of the resulting line is equal to 0.00300 atm/K. The line passes through the origin of the graph. What is ..
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