Compute the value of each partition function

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Reference no: EM13172227

Use the TST for the elementary reaction if the height of the barrier over the col is 9.61 kcal/mole. In the reaction the activated complex is linear with bond distances between D-H and H-H are both 0.930 Å. The vibrational wavenumber of the DH2 activated complex is 1766 cm-1 for the symmetric stretching mode and 840 cm-1 for the bending mode. The bond length and vibrational mode of H2 are 0.741 Åand 4400 cm-1, respectively. a) list the partition functions for each reactant and the activated complex based on the information above. b) Calculate the value of each partition function. c) Use the TST to calculate the rate constant for the reaction D + H2à DH + H

Reference no: EM13172227

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