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Molar Absorptivity and Beer's Law
4. A weak organic acid in its dissociated form (A-) absorbs at 375 nm with a molar absorptivity, ε, of 4.48×103 L/(mol?cm). The non-dissociated form of the acid (HA) does not absorb at 375 nm. At 375 nm, a 3.0×10-3 M solution of the acid in water has an absorbance of 0.462 in a 1.00 cm cell.a. What is the concentration of A- in this solution?b. What is Ka for this acid?
5. The molar absorptivity for the complex formed between bismuth (III) and thiourea is 9.32 x 103 L mol-1 cm-1 at 470 nm. Calculate the range pf permissible concentrations for this complex if the percent transmittance is to be greater than 15.0 % and less than 85.0 % in a 2.00-cm cell.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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