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Suppose CoQ (also known as ubiquinone) is reduced to CoQH2 by one of the iron-sulfur proteins, Fe-S(Fe2+), with a standard reduction potential Eo'= - 0.270 V at 37.0 oC. (Assume all values tabulated for 25 oC are unchanged at 37.0 oC; answer all questions below using this temperature.) (a) Write the relevant half-reactions and from these derive the balanced redox equation for the above reaction. (b) Calculate ?Eo'. (c) Calculate ?G o'. (d) Calculate the equilibrium constant, K. (e) Which side of the reaction (reactants or products or neither) is favored structurally? (f) Calculate the pH of the system that will generate a cell potential, ?E, of + 0.157 V when the ratio [Fe-S(Fe2+)]/[Fe-S(Fe3+)] = 2.25, [CoQ] = 8.17 x 10-4M, and [CoQH2] = 7.59 x 10-3M.
For the given reaction, 2 HCl (aq) + Ba(OH)2 (aq) BaCl2 (aq) + 2 H2O (l) 73.0 grams of HCl are allowed to react with 342 grams of BaCl2.
Sodium carbonate reacts with hydrochloric acid as shown below in an unbalanced chemical equation. What mass of CO2 is produced from the reaction of 2.94g Na2CO3 with excess HCL
What mass of sucrose should be combined with 521 of water to make a solution with an osmotic pressure of 8.15 at 285 ? (Assume the density of the solution to be equal to the density of the solvent.)
A solution is 89.8% by volume benzene(C6H6) in carbon tetrachloride at 20 degrees C. The vapor pressure of pure benzene at this temperature is 74.61 mmHg and it's density is 0.87865 g/cm^3;
A certain pesticide is fatal to fish fingerlings at a level of 0.5 parts per million in water. A leaking metal can containing 10.0 kg of the pesticide was dumped into a stream with a flow of 10.0 Liters per second moving at 0.7 km/hr.
how does temperature affect the equilibrium constant of the reaction between ethanoic acid and ethanol (condensation reaction at room temperature and pressure.
Important information about Thermochemistry, Glauber's salt, sodium sulfate decahydrate (Na2SO4 * 10H2O) undergoes a phase transition (that is melting or freezing) at a convenient temp of 32 degrees C
An unknown compound X, is thought to have a carboxyl group with a pka of 2.0 and another ionizable group with a pka between 5 and 8. When 75 ml of 0.1 M NaOH was added to 100 ml of a 0.1 m solution of X at pH 2.0, the pH increased to 6.72.
sample of unknown HCL solution reacts completely with Na2CO3 to form 15.1g CO2, What was the concentration of the HCL solution?
A metal bulb is filled with 10.2 g of CHCl3 and 0.322 g of CH4 (two gases). What is the total pressure in the bulb if the temperature is 345 C and the volume is 50.0 mL.
An aqueous solution containing 0.003 M NaCl and 0.005 M CaCl2 is mixed with the polysaccharide alginate to create a high-viscosity liquid that is a component of a wound dressing
What volumes of .200 M HCOOH and 2.00 M NaOH would make 300 mL of a buffer with the pH of one made from 475 mL of .200 M benzoic acid and 25 mL of 2.00 M NaOH?
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