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(1) 1 g of caffeine is soluble in 47 mL of water, 10 mL of dichloromethane, and 370 mL of diethyl ether (at 25 °C).
(a) Calculate the solubility (in grams/100 mL) of caffeine in these three solvents.
(b) Calculate partition coefficient of caffeine between water and each of two organic solvents.
(c) Can you use diethyl ether to extract caffeine from water? Why/why not.
(2) Tea contains several different organic compounds, which have diverse physiological effects on our organism. Look up and write down the structural formula of the three compounds present in tea: theophylline, theobromine, and (-) epicatechin. For your own,
A gaseous mixture of O2 and N2 contains 36.8% nitrogen by mass. What is the partial pressure of oxygen in the mixture if the total pressure is 685 mmHg.
A voltaic cell consists of an Au/Au3+ electrode (E° = 1.50 V) and a Cu/Cu2+ electrode (E° = 0.34 V). Calculate [Au3+] if [Cu2+] = 1.20 M and Ecell = 1.13 V at 25°C.
NO2 then interacts withUV light according to the following reaction. Classify this reaction as a synthesis, decomposition, single-displacement, or double-displacement reaction.
What is the HCl concentration if 69.7 mL of 0.350 M NaOH is required to titrate a 30.0 mL sample of the acid?
A an aqueous methanol (CH3OH) solution has a mole fraction of 0.430 of methanol. What mass of water would be present in 706 g of this solution?
The piston is then moved in and the heat rejected by the air reversibly at constant pressure until the volume is= initial volume. compute The net heat flow and the overall change in entropy?
Which of the following substances can act as a Bronsted acid in aqueous solution? (Select all that apply.)
An aqueous solution is 48.3% by mass hydroiodic acid, HI. The density of this solution is 1.6 g/ml at 20 C. How many grams of pure HI are there in 190.0 ml of this solution at 20.0 C?
For many reactions near room temperature, the rate and the rate constant approximately double for a 10 °C rise in temperature. What is the value of activation energy in kJ/mol for such a reaction?
What was the volume of the gas when the temp was changed to 50.0C and the new pressure was 760.0 torr.
A water skier is pulled by a net force of 135 N and has an acceleration of 1.8 m/s2. What is the mass of the skier.
Calculate the energy of a photon of wavelength 11.56 meters. (Planck's constant is 6.626 x 10-34 joule seconds; the speed of light is 2.998 x 108 m/s)
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