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Suppose life has been discovered on another planet in a distant solar system. Organelles corresponding to our mitochondria transform energy by a Mitchell-like chemiosmotic mechanism. The flow of electrons drives the production of a pH gradient in the same direction. The only difference is the H+-ATP stoichiometry. Given that the pH on the outside of the xeno-mitochondrial membrane is 6.014, the pH on the inside is 7.568, ?G for ATP synthesis is 12.85 kcal/mol, and the alien body temperature is 27.3oC, calculate how many protons are required to pass through the xeno-FoF1-ATP synthase complex to synthesize one ATP. Round off your answer to the nearest integral value. (Assume, as we have done in class, that sufficient "power" to synthesize ATP exists when ?G for transporting protons across the membrane equals ?G for ATP synthesis.)
A patient needs to take 625 of ibuprofen twice daily. The pills in the bottle are each 250. . How many pills does the patient need to take each time she wants the 625 dosage? Assume that these pills are scored and can be cut in half if necessary.
What mass of sucrose should be combined with 461 g of water to make a solution with an osmotic pressure of 8.85 atm at 310 K? (Assume the density of the solution to be equal to the density of the solvent.)
TNT(trinitrotoluene) decomposes exposively What volumes of Hydrogen gas and Nitrogen gas are produced if 5.8 liters of CO is produced ?
What is the concentration of X when the potential is 0.0490 V? Assume that the electrode follows the Nernst equation, the temperature is at 25°C, and that the activity coefficient of X is 1.
A 28.0-g sample of water at 260. K is mixed with 51.0 g water at 310. K. Calculate the final temperature of the mixture assuming no heat loss to the surroundings
To prepare 5.0 L of a 3.50 M solution of Potassium Hydroxide (KOH), how many grams of Potassium Hydroxide must be used?
What is the pH of a solution of a strong acide like tintric acid, HNO3, which is 5.6 x 10^-4 M? [HNO3 is a strong acide, so it is completly ionized in aqueous solution
It was found that 19.31 mL of an HCl solution are needed to react completely with 322 mL of a LiOH solution that has a pH of 11.56. What is the molarity of the HCl solution?
How many possible isomers could exist for diacetylferrocene? Explain. Calculate the volume of 3M aqueous sodium hydroxide needed to neutralize the acetic and phosphoric acids in the synthesis of acetylferrocene?
At a certain temperature, K = 9.1 10-4 for the following reaction. FeSCN2+(aq) Fe3+(aq) + SCN -(aq)
What is the mole fraction of acetone, C3H6O, in the vapor phase from a solution consisting of a mixture of acetone and ethyl acetate, CH3COOCH2CH3, at 30.00 °C, if the total pressure above the solution is 184.6 torr?
A fish tank holds 30.0 gal of water. Using a density of 1.0 g/mL for water, determine the number of pounds of water in the fish tank.
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