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In photosystem I, light energy is converted into chemical energy. Energy in the form of photons is absorbed by a chlorophyll complex P700 which donates an electron to A. The electron is passed down an electron-transport chain, at the end of which NADP+ is reduced. The reduction potentials of P700+, A and NADP+ at pH7 and 25 oC are 0.490V, -0.900V, and -0.350V respectively.
a) Calculate Eo of the reaction at 25oC: P700 + A --> P700+ + A-
b) Calculate ΔGo for the same reaction.
c) How many photons of 800 nm (1nm = 1 x 10-9 m) light are required?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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