Compute component fugacity coefficients in binary mixture

Reference no: EM13674274

Derive equations to compute component fugacity coefficients in a binary mixture using the virial equation of state truncated after the second virial coefficient. The mixture second virial coefficient is given as B = Y1B1 + Y2B2 + Y1Y2? 12 where? 12 = 2B12 – B1 – B2 B1 and B2 are the second virial coefficients of components 1 and 2, and B12 is the interaction second virial coefficient. Express the virial equation of state in the subsequent alternative form, truncated after the second virial coefficient: PV/RT = z = 1 + BP/RT Hint: The component fugacity coefficient in a mixture is a partial property, and is calculated as the partial derivative of the corresponding total property by respect to the number of moles of the component in question in the mixture.

Reference no: EM13674274

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