Classical limit for vibrations and rotations

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You have two identical containers at a fixed temperature. In one you have water vapor (H2O) and in the other you have carbon dioxide (CO2). In the high-temperature, classical limit for vibrations and rotations, meaning that (rotation angle << T) and (vibration angle <<T), and assuming you can ignore all excited electronic states, which of the following statements is true.

  • The molar heat capacity of the water is larger than the molar heat capacity of the carbon dioxide.
  • The molar heat capacity of the carbon dioxide is larger than the molar heat capacity of the water
  • The molar heat capacity of the water and the carbon dioxide are the same.

Reference no: EM132052350

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