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Problem: Carbon forms two stable oxides, CO and CO2. Lead forms three oxides: yellow PbO, black PbO2 and red Pb3O4.
a. Carbon monoxide burns readily in air. Heating black lead oxide produces oxygen gas, leaving a yellow residue.
i. Suggest a balanced equation for each reaction.
ii. Explain how these two reaction illustrate the relative stabilities of the +2 and +4 oxidation states down Group IV.
b. Red lead oxide contains lead atoms in two different oxidation states.
i. Suggest what these oxidation states are, and calculate the ratio in which they occur in read lead oxide.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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