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a) In an attempt to determine an accurate value of the gas constant, R, a student heated a container of volume 20.000 dm3 filled with 0.251 32 g of helium gas to 500°C and measured the pressure as 206.402 cm of water in a manometer at 25°C. Calculate the value of R from these data. (The density of water at 25°C is 0.997 07 g cm-3;
(b) The following data have been obtained for oxygen gas at 273.15 K. Calculate the best value of the gas constant R from them and the best value of the molar mass of O2.
p/atm
0.750 000
0.500 000
0.250 000
Vm/(dm3 mol-1)
29.9649
44.8090
89.6384
?/(g dm-3)
1.07144
0.714110
0.356975
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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