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1. Calculate the standard state potential (E0) and the equilibrium constant (K) for the following redox reaction: IO3-(aq) + I-(aq) ↔ I2(s) acidic solution
Assume that [H3O+] is 1.0 M.
IO3-/I2 = 1.195 V; I-/I2 = 0.5355 V
Notes: This redox reaction is not balanced. You will need to balance it before calculating its standard state potential.
Clearly show and indicate the oxidation and reduction half-reactions as well as the overall reaction.
2. Calculate the potential for the following (unbalanced) redox titration at 25 oC:
Ti2+ (aq) + Fe3+ (aq) → Ti3+ (aq) + Fe2+ (aq)
Fe3+/ Fe2+ = 0.771 V; Ti3+/ Ti2+ = -0.37 V
When 12.5 ml of 0.010 M of the titrant (underlined) is added to 25.0 ml of 0.010 M analyte.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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