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Iron(III) is polarographically reduced to iron(II)at potentials more negative than about +0.4V versus SCE and is further reduced to iron(O) at -1.5V (vs SCE). Iron(II) is also reduced to metal at -1.5V. A polarogram is run using a dropping mercury electrode on a solution containing both Fe3+ and Fe2+.A current is recorded at zero applied volts, and its magnitude is 12.5μA. A wave is also recorded with E1/2 equal to -1.5V versus SCE, and its height is 30.0μA. Calculate the relative concentrations of Fe3+ and Fe2+ in solution.
The refining of aluminium from bauxite ore proceeds by the overall reaction: 2Al2O3 + 3C --> 4Al + 3CO2.
Determine the microcanonical partition function, omega. Determine fundamental relation of system, using Stirling's approximation Determine the energy and heat capacity for the system as a function of temperature using Stirling's approximation. Det..
Determining mechanism of a reaction, 2,3-Dimethyl-2,3-butanediol (pinacol), upon heating in aqueous acid, rearranges to form 3,3-dimethyl-2-butanone (pinacolone)
Determine the percent yield if An 8.50 grams sample of Ammonia gives 12.0 g of Nitric Oxide?
Consider the gas-phase reaction A + 2B 2C + D. Starting with 1.0 mole of A and 1.0 mole of B in 2.0 liter container, the reaction proceeds to equilibrium at T = 103C with 8.6 × 10-2 moles of C now present.
Thermodynamic Processes. a volume of 20 cu ft of air at pressure of 50 psig is heated and expanded to 30 cu ft and 40psig find the change in the energy of air in joules.
The enthalpy of combustion of acetylene C2H2 is C2H2(g) + 5/2O2(g) ->2CO2(g) + H2O(l) H°rxn= -1299 kJ Calculate the enthalpy of formation of acetylene, given the following enthalpies of formation H°f[CO2(g)] = -393.5 kJ/mol ,H°f[H2O(l)] = -285.8 k..
Specific rotation of α and β -D-glucose - Determine the percentage of each anomer at equilibrium.
Chlorine gas can be produced commercially by passing an electric current through a con- centrated solution of sodium chloride (brine).
How many ml of 0.05 M HCl solution would be required to completely neutralize 25.0 ml of 1.0 M Ba(OH)2 solution?
What is the pH of pure water in equilibrium with 1 atmosphere of carbon dioxide at 25?C?
If 155mL of wet {grm{H}}_2 is collected over water at 24 ^circ {rm C} and a barometric pressure of 739torr , how many grams of {grm Zn} have been consumed.
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