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Question 1: Consider a chemical reaction: A-4 Product
Time / min
Concentration of [A], M
Rate , M/min
0
0.012
4.20 x 10 -5
50
0.0101
3.52 x 10 -5
100
0.00846
2.96 x 10 -5
150
0.0071
2.49 x 10 -5
200
0.00596
2.09 x 10 '
250
0.005
1.75 x 10 -5
300
0.0042
1.48 x 10 -5
350
0.00353
1.23 x 10 -5
400
0.00296
1.04 x 10 '
(i) Determine the order of the reaction using integration and graphical method.
(ii) Calculate the rate constant and half-life of the reaction
(iii) Calculate the half-life, if the initial concentration is increased from 0.012 to 0.12 M.
(iv) Draw a graph of half-life vs concentration of reactant
Question 2: Explain the formation of F2 molecule according to Lewis theory, Valance Bond Theory and Molecular Orbital Theory.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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