Calculate the rate constant and half-life of the reaction

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Question 1: Consider a chemical reaction: A-4 Product

Time / min

Concentration of [A], M

Rate , M/min

0

0.012

4.20 x 10 -5

50

0.0101

3.52 x 10 -5

100

0.00846

2.96 x 10 -5

150

0.0071

2.49 x 10 -5

200

0.00596

2.09 x 10 '

250

0.005

1.75 x 10 -5

300

0.0042

1.48 x 10 -5

350

0.00353

1.23 x 10 -5

400

0.00296

1.04 x 10 '

(i) Determine the order of the reaction using integration and graphical method.

(ii) Calculate the rate constant and half-life of the reaction

(iii) Calculate the half-life, if the initial concentration is increased from 0.012 to 0.12 M.

(iv) Draw a graph of half-life vs concentration of reactant

Question 2: Explain the formation of F2 molecule according to Lewis theory, Valance Bond Theory and Molecular Orbital Theory.

Reference no: EM133089325

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