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A solution is prepared by dissolving 0.075 mol of iodoacetic acid (Ka = 6.68×10-4) and 0.030 mol of sodium iodoacetate in water to a total solution volume of 1.00 L.
1) First, calculate a pH for the solution by assuming that the concentrations of ICH2CO2H and ICH2CO2-are equal to the formal concentrations of the substances dissolved.
2) Next, calculate the pH for the solution based on the equilibrium concentrations of ICH2CO2H and ICH2CO2-.
3) Use the Henderson-Hasselbalch approximation to calculate the pH of a solution prepared by dissolving in water, to a final volume of 1.00 L, 0.200 mol of iodoacetic acid, 0.040 mol of sodium iodoacetate, 0.080 mol of HNO3and 0.080 mol of Ca(OH)2.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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