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1 - Compute the internal energy change if an ideal gas expands from a volume of 2.3 L to 6.4 L against a pressure of 1.8 atm and 330 J of heat are transferred from the surroundings to the system.
2 - A sample of metal weighing 33.6 g is heated to 99.4 oC and transferred to a calorimeter containing 51.2 g of water at an initial temperature of 19.8 oC. The final temperature in the calorimeter is 25.0oC. What is the specific heat of the metal?
3 - Given the following equation for the combustion of ammonia, compute the enthalpy change if 2.2 moles of ammonia are burned in excess oxygen 4NH3(g) + 5O2(g) ? 4NO(g) + 6H2O(g) ?H = ?904 kJ/mol
4 - 0.06 moles each of Ag+(aq) and Cl?(aq) react to form AgCl(s) precipitate in a calorimeter containing 48.8 g of water and the temperature increases from 20.1 oC to 39.4 oC. Compute the enthalpy of reaction per mole of Ag+.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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