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Problem 8.14: At 100 °C, water (w) and nitrobenzene (n) are only partially miscible. At this temperature, the solubility of nitrobenzene in water is 0.147 mol %, while the solubility of water in nitrobenzene is 8.3 mol %. a) Assuming that each liquid phase behaves ideally with respect to the concentrated species (that is, w 1, in the water-rich phase and n 1 in the nitrobenzene-rich phase), calculate the activity coefficient of each component at infinite dilution. b) Show that if boiling occurs under constant pressure, the boiling temperature must remain constant until one of the two liquid phases completely evaporates. c) One hundred mol of the water-rich phase are mixed with 100 mol of the nitrobenzene-rich phase at 100°C and the pressure is adjusted until boiling starts. What is the pressure? d) Calculate the composition of the vapor phase in the previous part. e) If boiling continues indefinitely, which liquid phase will disappear first? f) Draw a qualitative Pxy graph for this system at 100 °C. Show all the important features on the graph. The saturation pressure of nitrobenzene at 100 °C is 21 mmHg.
A natural rubber compounded is proposed for a bushing application. Stress analysis indicates that the structure requires a tensile modulus of 5 Mpa. In terms of percentage, how much dicumyl peroxide must be used in the compound to achieve the desired..
1discuss an incident fire spill explosion etc that you have experienced or research one on the internet professional
Calculate the atomic weight (in amu) of an element (X), given the following data: 24X : 24.000 amu at 0.7879 fractional abundance 26X : 26.000 amu at 0.1017 fractional abundance 25X : 25.000 amu at 0.1113 fractional abundance
The feed is a saturated liquid at 330 kPa. The recovery of toluene in the distillate should be greater than 99%, and the recovery of ethylbenzene in the bottoms should be greater than 99%.
Estimate the annual operating cost of providing refrigeration to a condenser with duty 1.2 MW operating at -5 ºC. The refrigeration cycle rejects heat to cooling water that is available at 40 ºC, and has an efficiency of 80% of the Carnot cycle ef..
All other conditions are the same as those specified in Example 5 of this chapter, except that Bi is not given. 8. Present a detailed derivation of Eq. (481 in this chapter, using, as a starting point, any of the other equations that are given.
What is the maximum work ( in Btu/lb) obtainable from an adiabatic expansion of ethylene gas through a turbine from 1000 psi and 340 F to a pressure of 100 psi.
Calculate the instantaneous and rms values of the voltage induced in a 150-turn coil on the armature, if the axial length of the armature and its inner diameter are both 100 mm.
Determine the original composition of the feed mixture and the composition of the resulting extract layer. free solution
Chemical X costs $0.09 per pound. Chemical Y costs $0.04 per pound. Chemical Z sells for $0.80 per pound. If one-half of the selling price for chemical Z is due to costs other than for raw materials, what is the maximum profit obtainable per pound..
Suppose a membrane has an active Na-K pump with and Cm = 1mF as shown in Figure 11.15. Design a stimulus that will drive Vm to threshold at 3 ms. Assume that the threshold potential is 40mV.
The characteristics of a sigmoidal curve are dependent upon the constants and the stimulus. Change the constants and observe the effects. What range of values leads to a curve that appears to be hyperbolic?
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