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Quinone undergoes a reversible reduction at a voltammetric working electrode. The reaction is
(a) Assume that the diffusion coefficient for quinone and hydroquinone are approximately the same and calculate the approximate half-wave potential (versus SCE) for the reduction of hydroquinone at an ROE from a solution buffered to a pH of 7.0.
(b) Repeat the calculation in (a) for a solution buffered to a pH of 5.0.
a homogenous cylinder begins to roll without slipping down a plane that is inclined at an angle theta. the moment of
a closed well insulated tank contains 10 kg of air at 300 k. an electric motor drives a propeller inside the tank
Problem 1: A projectile is launched at point A with initial velocity 120 m/s and initial angle 40o as shown. In addition to the gravity, the wind exerts a horizontal acceleration of 2 m/s2 to the left on the projectile. Determine the flight time fo..
The exhaust nozzle of a jet engine expands air at 388 kPa and 174 C adiabatically to 95 kPa. Determine the air velocity at the exit when the inlet velocity is low and the nozzle isentropic efficiency is 96 percent.
A helical compression spring is wound using QQ&T A229 wire. The spring is needed to support a 25-lbf load after being compressed 1.5 in. Because of assembly considerations, the solid height cannot exceed 1.5 in and the free length cannot be more than..
a cylinder having a piston restrained by a linear spring of spring constant 15 knm contains 0.5 kg of saturated vapor
Consider the conditions of Example 9.3, including the effect of adding insulation of thickness t and thermal conductivity k = 0.035 W/m · K to the duct. We wish to now include the effect of radiation on the outer sur- face temperatures and the tot..
the eagle zr tire shown in the figure 1 is used on a corvette j with a test weight of 3500 lb. and having a 5248 weight
Komodo dragons are the largest lizards known to man. A 250-pound dragon can eat enough food to increase it body weight by 1/2. Which number sentence could be used to find w, the weight of a k0modo dragon after increasing it body weight by 1/2?
a piston-cylinder device contains 01.440 kg of refrigerant-134a at -10 degrees celsius. the piston that is free to move
There are two thermal reservoirs: the hot reservoir is at 1200 K and the cold reservoir is at 600 K. If you wanted to transfer 100 kJ from on reservoir to the other, what would the change in entropy of the two reservoirs be?
A piston-cylinder device containing .1 Kg of saturated liquid water, initially at 1 bar, is heated at constant pressure until the temperature is 140C. an electrical heater within the device is turned on and is allowed to pass a current for 5 min from..
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