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Question: A quantity of oxygen gas is contained in a vessel of volume V = 1m3 at a temperature of T = 300K and a pressure of P. The vessel is connected
to a mercury-filled tube as shown in Fig. Note that the upper end of the tube is open to the atmosphere.
a. Is P greater or lesser than 1 atm? Calculate P in units of Torr and also pascals.
b. If the temperature of the gas is doubled, keeping V constant, by what factor does each of the following change?
i. density (g/cm3)
ii. average kinetic energy of a molecule
iii. rate of molecular collision with the walls
iv. vrms v. mass of 1 mole of gas
c. By means of a small pump the gas pressure is reduced to 100 Torr, while the temperature and volume remain fixed at 300K and 1m3. What then is the average kinetic energy of 1 molecule of the gas? Express your final answer in eV.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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