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Approximation for the translational partition function

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Explore the conditions under which the 'integral' approximation for the translational partition function is not valid by considering the translational partition function of an H atom in a one-dimensional box of side comparable to that of a typical nanoparticle, 100nm. Estimate the temperature at which, according to the integral approximation, q = 10 and evaluate the exact partition function at that temperature.

Reference no: EM132776164

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