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1) Let's assume that, as a preventative measure, you added 2 drops of the Vitride solution to your bromobenzene/Mg mixture when forming the Grignard reagent, but that your ethereal solution was completely dry (i.e. no water). That Vitride would reduce the 2-methylpropanal when it is added to the Grignard reagent. What mass of reduced aldehyde would be formed after the workup of the reaction? HINT: Look carefully at the structure of Vitride. 2) Assuming Vitride reduced the aldehyde faster than the Grignard reagent, and also assuming the reduced aldehyde acted just like your desired product during the isolation of 2-methyl-3-heptanol, what is the mass percent of the reduced aldehyde in your product mixture? 3)It's generally a bad idea to add extra reagents that are capable of reacting to a reaction due to the possibility of multiple products that are inseparable. ?? ? Comment on whether or not it is/was worthwhile to add Vitride to a sluggish Grignard reagent formation based on your answer to part 2 above as well as based on how you characterized the product.
Isopropyl Iodide can be used in acetoacetic esther synthesis in the presence of NaOET to form 4-methyl-2-pentanone. How does this occur? P.S. I tried to use the chem software to diagram this reaction but failed miserably :P
Calculate the enthalpy change associated with the conversion of 25.0 grams of ice at -4.00°C to water vapor at 110.0°C. The specific heats of ice, water, and steam are 2.09 J/g-K, 4.18 J/g-K, and 1.84 J/g-K, respectively. For H2O, Hfus = 6.01 kJ/m..
This solution was back-titrated with a 0.0370 M Ga3 solution until all the EDTA reacted, requiring 11.0 mL of the Ga3 solution. What was the original concentration of the V3 solution?
Write the expression for the reaction rate in terms of d[NOCl]. c. The concentration of NOCl drops from 0.580 M to 0.238 M in 8.00 min. Calculate the average rate of reaction over this time interval.
what must be the atomic mass of the metal mnbsp if a sample of the compound mso4 weighing 0.1131 g reacts with barium
consider the hypothetical elements x y and z with the following lewis formulas. x with seven electron dots around it y
A gas mixture composed of helium and argon has a density of 0.670 g/L at 755 mm Hg and 298K. What is the composition of the mixture by mass
Lead has a face-centered cubic lattice with all atoms at the lattice points and a unit-cell edge length of 495.0pm its atomic mass is 207.2 amu what is the density of lead?
N2O4(g) + KCl(s) → NOCl(g) + KNO3(s) Find out oxidation number of each and find which one is reduced and which one is oxidized by Using oxidation number concept? Also write net ionic equation and ionic equation.
Nitroglycerin (C3H5(NO3)3 is a stock sensitive liquid that detonates that is it decompresses explosively to form N gas, steam, carbon dioxide gas, and oxygen gas. Calculate the volume of product gases at 215 KPa, and 275 Celsius from the detinatio..
Methanol and sodium sulfate are by-products of synthesis of salicylic acid. during which step of the synthesis would these compounds have been separated from the final product? explain your answer based on any relevant properties of salicylic acid..
The molar solubility of a salt with the general forumula. M2Q, is 2.3 x 10^-3 mol/L. A. What is the Ksp of the salt?. What is the free energy change for the dissolution of the salt at 25C?
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