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A solution containing 3.47mM X (analyte) and 1.72 mM S (standard) gave peak areas of 3473 and 10222, respectively, in a chromatographic analysis. Then 1.00ml of 8.47mM S was added to 5.00ml of unknown X, and the mixture was diluted to 10.0ml. This solution gave peak areas of 5428 and 4431 for X and S, respectively.
a. Calculate the response factors for the analyte.
b. Find the concentration of S (mM) in the 10.0ml of mixed solution
c. Find the concentration of X (mM) in the 10.0ml of mixed solution
d. Find the concentration of X in the original unknown
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The standard free energy of activation of a reaction A is 73.9kJ/mol-1 (17.7 kcal mol-1) at 298 K. Reaction B is one million times faster than reaction A at the same temperature. The products of each reaction are 10.0 kJ mol-1 (2.39 kcal mol-1) mo..
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