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Problem- a) Give a mechanism for the reaction of a ketone with semicarbazide to form a semicarbazone
b) Why is sodium acetate added in the preparation of the semicarbazone of bezalacetone
c) Write a structure for the product formed by condensing benzaldehyde with acetophenone
d) Write stereo structures for all possible stereoisomers of bezalacetone and dibenzalacetone. In each system, only one stereoisomer is the actual product. Which isomer is formed and why. Explain
I need help for above questions. Show each steps for the above problems.
A biological membrane contains N ion channl proteins. Explain the fraction of time that any one protein is open to permit ions to flow trough is q. Express the probability P (m, N) that m of the channels will be open at any given time.
what the volume of 0.109m HNO3 that is required to reat completely with 2.5g Barium hydroxide
The gas-phase decomposition of N2O5 is the first-order process with a rate constant of 1.50 x 10^-3s^-1 at 55*C. The decomposition is:
Calculate the osmotic pressure of a solution containing 25.9g of glycerin (C3H8O3) in 243.5mL of solution at 310K.
How much heat is released when 6.38 grams of Ag(s) reacts by the equation shown below at standard state conditions. 4Ag(s) + 2H2S(g) +O2(g) --> 2Ag2S(s) + 2H20(l)
what nucleophile could be used to react with butyl iodide to prepare the following compound? if your answer is a metal
Since phosphate ionization of 2.14, 6.86 and 12.4. you make stock buffer 500mM in 1L. You decide to make one stock pH 6.5 and the other ph 7.2 How many mmols of what type of phosphate componet do you add to each of these buffers?
is it possible to synthesize 1-bromo-4-nitrobenzene by reacting bromobenzene with a mixture of nitric and sulfuric acids. However, 1-bromo-4-nitrobenzene is not obtained if nitrobenzene is reacted with Br2/FeBr3. Explain the difference
Give the balanced equation for the reaction- exothermic formation of 1 mol of sodium chloride from its elements
When 2.0 x 10^2 mole of nicotinic acid (a monoprotic acid is dissolved in 350 mL of water, the pH is 3.05. What is the Ka of nicotinic acid
a solution of cyclohexane and an unknown solute freezes at 3.3c and 1atm of pressure. calculate the freezing point depresson of the solution
A 0.0100 L sample of H2SO4 (Sulfuric Acid) was titrated with 0.150 M NaOH. It took 23.3 mL of NaOH from the buret -- that's 0.0233 L -- to reach the titration endpoint.
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