Werner's Coordination theory, Coordination Compounds, Chemistry Assignment Help

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Bonding in co-ordination compounds (Werner's Coordination theory)

         The scientist named Werner was able to explain the bonding in complex.

         Primary valency (Pv) : This is non- directional and ionizable. Actually it is the positive charge on the metal ion.

         Secondary valency  (Sv) : This is directional and non- ionizable. It is equal to number of the ligand atoms co-ordinated to the metal (co-ordination number). Example of it can be seen in the table which is drawn below :

1553_bonding in coordination compounds1.png 

   The nature of the complex may be understood by treating the above complexes with excess of AgNo3

2027_bonding in coordination compounds.png

            The nature of bonding between central metal atom and ligands in the coordination sphere has been explained by the three well-known theories.  

 

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