Unsaturated dicarboxylic acids
The molecular formula of the simplest unsaturated dicarboxylic acid is HOOC.CH=CH.COOH This formula, however represents two chemical compounds, maleic acid and fumaric acid, which are geometrical isomers.
(1) Methods of Preparation of Maleic Acid
(i) By catalytic oxidation of 2-butene or benzene
(2) Methods of Preparation of Fumaric Acid
(i) From maleic acid :
(ii) By oxidation of furfural with sodium chlorate
(iii) By heating malic acid at about 150°C for long time
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