Unsaturated dicarboxylic acids Assignment Help

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Unsaturated dicarboxylic acids

         The molecular formula of the simplest unsaturated dicarboxylic acid is HOOC.CH=CH.COOH This formula, however represents two chemical compounds, maleic acid and fumaric acid, which are geometrical isomers.

            1862_unsaturated dicarboxylic acid.png

         (1) Methods of Preparation of Maleic Acid

         (i) By catalytic oxidation of 2-butene or benzene

         2360_unsaturated dicarboxylic acid1.png

 

         (2) Methods of Preparation of Fumaric Acid

         (i) From maleic acid :     1223_unsaturated dicarboxylic acid2.png

         (ii) By oxidation of furfural with sodium chlorate

1503_unsaturated dicarboxylic acid3.png

         (iii) By heating malic acid at about 150°C for long time

         1759_unsaturated dicarboxylic acid4.png

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