Trihydric Phenols, Hydroxy Compounds Assignment Help

Assignment Help: >> Phenol (Carbolic acid) >> Trihydric Phenols, Hydroxy Compounds

Trihydric Phenols : Three trihydroxy isomeric derivatives of benzene are Pyrogallol (1, 2, 3), hydroxy quinol (1, 2, 4) and phloroglucinol (1, 3, 5).

         Pyrogallol is generated by heating aqueous solution of gallic acid at 220°C.

475_Trihydric alcohol.png

Phloroglucinol is created from trinitrotoluene (TNT) by following sequence of reactions.

 

2035_Trihydric alcohol1.png481_Trihydric alcohol2.png

         Hydroxyquinol is created by the alkaline fusion of hydroquinone in air.

  519_Trihydric alcohol3.png

The three isomers are colourless crystalline compounds. All are soluble with water and their aqueous solutions give characteristic colour with FeCl3 (Red, brown or bluish violet). Alkaline solutions absorb oxygen rapidly from air.

 

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