Transition state theory

(i) According to the transition state theory activated complex is supposed to be in equilibrium with reactant molecules.

(ii) Once if transition state is formed it can either return to the initial reactants or proceeds to form products.

(iii) Assuming that once formed transition state proceeds to the products we can say that rate is proportional to the concentration of transition state.

Mathematically, Rate   Transition state

Rate= Constant × Transition state

(iv) The activation energy for the forward reaction,    and activation energy for the reverse reaction     are related to enthalpy? H of reaction by the equation 

(a)  For the endothermic reactions, ΔH>0 such that   < 

(b)  For the exothermic reaction, ΔH<0  such that    >    .

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