Tetra-halides (Carbon tetrachloride, CCl₄)

            It is very useful tetrahalogen derivative of methane.

         (1) Manufacture

(i) From methane :     

         (ii) From carbon disulphide :

         S₂Cl₂ further reacts with CS₂ to form more of carbon tetrachloride.

         Carbon tetrachloride is separated out by fractional distillation. It is refined with sodium hydroxide and then distilled to get a pure sample.

         (iii) From propane :

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