Tests of phenol, Liebermann's nitroso reaction, Hydroxy Compounds Assignment Help

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Tests of phenol

            (i) Aqueous solution of phenol provides a violet colouration with a drop of ferric chloride.

         (ii) Aqueous solution of phenol provides a white precipitate of 2, 4, 6-tribromophenol with bromine water.

         (iii) Phenol produces Liebermann's nitroso reaction.

         Phenol in conc. sulphuric acid  254_test of phenol.png  Red colour  31_test of phenol1.png  Blue colour

 

       (iv) Phenol combines with phthalic anhydride in presence of conc.H2SO4 to form phenolphthalein which gives pink colour with alkali, and needed as an indicator.

       (v) With sodium hypochlorite and ammonia, phenol gives blue colour.

 

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