Tests of iodoform
(i) With AgNO3 : CHI3 gives a yellow precipitate of AgI.
(ii) Carbylamine reaction : CHI3 on heating with primary amine and alcoholic KOH solution, gives an offensive smell of isocyanide (Carbylamine).
(iii) Iodoform reaction : With I2 and NaOH or I2 and Na2CO3, the iodoform test is mainly given by ethyl alcohol (CH3CH2OH) acetaldehyde a-methyl ketone or 2-one secondary alcohols or 2-ol (-CHOH.CH3) and secondary alkyl halide at C2(-CHCICH3). Also lactic acid (CH3-CHOH-COOH), Pyruvic acid and methyl phenyl ketone give this test.
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