Tests for Acetone, Aldehydes and Ketones Assignment Help

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Tests for Acetone

(i) Legal's test : When a few drops of freshly prepared sodium nitroprusside and sodium hydroxide solution are added to an aqueous solution of acetone, a wine colour is obtained which changes to yellow on standing.

(ii)  Indigo test : A small amount of orthonitrobenzaldehyde is added to about  2 ml. of acetone and it is diluted with KOH solution and stirred. A blue colour of indigotin is produced.

(iii) Iodoform test : Acetone gives iodoform test with iodine and sodium hydroxide or iodine and ammonium hydroxide.

 

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