Styrene (C6H5CH=CH2)
It is present in storax balsam and coal-tar in traces.
(1) Preparation
(i) Dehydrogenation of side chain of ethylbenzene :
(ii) Decarboxylation of cinnamic acid : That is the laboratory preparation and involves heating of cinnamic acid with a small amount of quinol.
(iii) Dehydration of 1-phenyl ethanol with H2SO4 :
(iv) Dehydration of 2-phenyl ethanol with respect to ZnCl2:
(v) Dehydrohalogenation of 1-phenyl-1-chloro ethane: On heating with alcoholic potassium hydroxide, a molecule of hydrogen chloride is eliminated by the chloroderivative.
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