Separation of alkane, alkene and alkyne
The gaseous mixture is passed through ammonical cuprous chloride solution. The alkyne (acetylene) reacts with Cu2Cl2 and forms a red precipitate. It is filtered. The alkyne or acetylene is recovered by decomposition of the precipitate with an acid.
The remaining gaseous mixture is passed through concentrated H2SO4. Alkene is absorbed. The Hydrogen sulphate derivatives is heated at 170oC to regenerate ethene.
The methane or ethane is left behind unreacted.
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