Screening effect & Shielding effect, Chemistry Assignment Help

Assignment Help: >> Chemical Periodicity or Periodic Table >> Screening effect & Shielding effect, Chemistry

The screening effect also called as shielding effect

A valence-electron in a multi-electron atom is attracted by the nucleus, and is repelled by electrons of the inner-shells. The collective effect of this attractive and repulsive force acting upon the valence-electron experiences less attraction from the nucleus. This is known as shielding or screening effect. The magnitude of screening effect depends upon the number of the inner electrons, that is higher the number of the inner electrons, greater will be the value of screening effect. The screening effect constant can be denoted by the symbol437_effective nuclear charge1.png can be determined by the Slater's rules.

Magnitude of the screening constant in case of the s- and p- block elements increases in the period as well as in the group as atomic number increases.

Effective nuclear charge

Because of the screening affect the valence electron experiences less attraction towards nucleus. This brings decrease in the nuclear charge (Z) actually present on the nucleus. The reduced nuclear charge is termed effective nuclear charge and is represented by Z+. It is related to actual nuclear charge (Z) by the following formula,

573_effective nuclear charge.png here 437_effective nuclear charge1.png is screening constant.

It is observed that magnitude of effective nuclear charge increases in a period when we move from left to right.

In the subgroup of ordinary elements the magnitude of effective nuclear charge remains almost the same.

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