Salicylic acid [O-Hydroxy benzoic acid];
Salicylic acid is present in many essential oils in the form of esters. Oil of winter green is a methyl ester of salicylic acid.
(1) Methods of preparation
(i) Kolbe Schmidt reaction
It is a commercial method. The reaction yields both o- and p- isomers. Salicylic acid is more volatile and separated by steam distillation.
(ii) Reimer-Tiemann reaction
(iii) From benzene derivatives
(a) 
(b) 
(c) 
(d) 
(e) 
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