Reduction of Alkyne : Alkynes add on hydrogen in presence of suitable catalysts like finely divided Ni, Pd.
If the triple bond is not found at the end of the carbon chain of the molecule, the alkene formed may be cis and trans depending upon the choice of reducing agents.
With Na/NH3 or Li/NH3 in (liquid ammonia) trans alkene is almost an exclusive product while catalytic reduction at alkyne affords mainly cis alkenes.
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