Properties of Allyl iodide or 3-iodopropene-1 : It is a colourless liquid. It boils at 103.1°C.The halogen atom in allyl iodide is quite reactive. The p-orbital of the halogen molecules does not interact with Π-molecular orbital of the double bond because these are separated by a saturated sp3-hybridized carbon molecules. Thus, the halogen molecules in allyl halides can be easily replaced and the reactions of allyl halides are similar to the reaction of alkyl halides.
In terms of valence bond approach, the reactivity of halogen molecules is because of ionisation to yield a carbonium ion which can stabilize by resonance as shown below,
Substitution reactions : Firstly Nucleophilic substitution reactions occur,
Addition reactions : Electrophilic addition equilibrium take place in accordance to Markownikoff's rule.
Allyl iodide is widely used in organic synthesis.
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