Properties of Allyl iodide or 3-iodopropene-1, Chemistry Assignment Help

Assignment Help: >> Allyl iodide or 3-iodopropene-1 >> Properties of Allyl iodide or 3-iodopropene-1, Chemistry

Properties  of Allyl iodide or 3-iodopropene-1 : It is a colourless liquid. It boils at 103.1°C.The halogen atom in allyl iodide is quite reactive. The p-orbital of the halogen molecules does not interact with Π-molecular orbital of the double bond because these are separated by a saturated sp3-hybridized carbon molecules. Thus, the halogen molecules in allyl halides can be easily replaced and the reactions of allyl halides are similar to the reaction of alkyl halides.

            In terms of valence bond approach, the reactivity  of halogen molecules is because of ionisation to yield a carbonium ion which can stabilize by resonance as shown below,

         145_properties of allyl iodide.png

         Substitution reactions : Firstly Nucleophilic substitution reactions occur,

 

 1130_properties of allyl iodide1.png 

         Addition reactions : Electrophilic addition equilibrium take place in accordance to Markownikoff's rule.

         2289_properties of allyl iodide2.png

         Allyl iodide is widely used in organic synthesis.

 

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