Picric acid (2, 4, 6-trinitrophenol) and Preparation Assignment Help

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Picric acid (2, 4, 6-trinitrophenol)

   Preparation : It is obtained when phenol is treated with conc. HNO3. However, the yield is much reduced. It is generated on an industrial scale :

   (i) From chlorobenzene

1946_picric acid.png 1198_picric acid1.png  

   (ii) From phenol through disulphonic acid

693_picric acid2.png

   (iii)1240_picric acid3.png

 

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