Physical Properties
(i) Physical state : Alkanes are colourless, odourless and tasteless.
Alkanes State
C1-C4 Gaseous state
C5-C17 Liquid state [Except neo pentane which is gas]
C18 and above Solid like waxes
(ii) Density : Alkanes are lighter than water.
(iii) Solubility : Soluble in organic solvents and not soluble in water, solubility 1/ Molecular Mass
(iv) Boiling points and Melting points : Melting points and boiling points. Molecular volume 1/ No. of branches
Alkane :
|
C3H8
|
C4H10
|
C5H12
|
C6H14
|
C7H16
|
C8H18
|
M.P.(K) :
|
85.9
|
138
|
143.3
|
179
|
182.5
|
216.2
|
- Melting points of even > Odd no. of carbon atoms, this is due to, the alkanes with even number of carbon molecules have more symmetrical structure and result in closer packing in the crystal structure as compared to alkanes with odd number of carbon atoms.
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