Nomenclature of organic compounds-Trivial System, Organic Chemistry Assignment Help

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Nomenclature of organic compounds

         Nomenclature means the assignment of names to organic compounds. There are two main systems of nomenclature of organic compounds.

1. Trivial System

2. IUPAC System

        Trivial system : This is the oldest system of naming organic compounds. The trivial name was generally based on the source, some property or some other reason. Quite frequently, the names chosen had Greek or Latin roots. As given,

         (i) Acetic acid derives its name from vinegar of which it is the chief constituent (Latin : acetum = vinegar).

       (ii) Formic acid was named as it was obtained from red ants. The Greek word for the red ants is formicus.

       (iii) The names oxalic acid (oxalus), malic acid (pyrus malus), citric acid (citrus) have been derived from botanical sources given in parentheses.

       (iv) Urea and uric acid have derived their names from urine in which both are present.

       (v) The liquid obtained by the destructive distillation of wood was named as wood spirit. Later on, it was named methyl alcohol (Greek : methu = spirit; hule = wood).

       (vi) Names like glucose (sweet), pentane (five), hexane (six), etc. were derived from Greek words describing their properties or structures.

       (vii) Methane was named as marsh gas because it was produced in marshes. It was also named as fire damp as it formed explosive mixture with air.

 Table: Common or trivial names of some organic compounds.

Compound

Common name

Compound

Common name

CH4

Methane

CHCl3

Chloroform

C2H2

Acetylene

CHI3

Iodoform

H3CCH2CH2CH3

n-Butane

CH3CN

Acetonitrile

(H3C)2CHCH3

Isobutane

CH3COOH

Acetic acid

(H3C)4C

Neopentane

C6H6

Benzene

HCHO

Formaldehyde

C6H5CH3

Toluene

(H3C)2CO

Acetone

C6H5NH2

Aniline

CH3CH2OH

Ethyl alcohol

C6H5OH

Phenol

CH3CONH2

Acetamide

C6H5OCH3

Anisole

CH3OCH3

Dimethyl ether

C6H5COCH3

Acetophenone

(CH3CH2)2O

Diethyl ether

C6H5CONH2

Benzamide

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