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Nitrenes (R - N : )

         (1) The nitrogen analogous of carbenes are known as nitrenes.

         (2) There is possibility of two spin structure for nitrenes depending on whether the two non-bonding electrons (the normal nitrogen lone pair remains paired) have their spins paired or parallel.

702_nitrene1.png


         (3) In general nitrenes obey Hunds rule and the ground state triplet with two degenerate sp-orbitals containing a single electron each.

 

2438_nitrene.png

         (4) Nitrenes can be created, in situ, by the given methods,

(i) By action of Br2 in presence of a base on a 10 amide (Hofmann-bromamide reaction),

2487_nitrene2.png

 

         (ii) By decomposition of azides in presence of heat or light.

890_nitrene3.png

         (iii) Unsubstituted nitrene 2196_nitrene4.pngcan be obtained by photolysis of (or by passing electric discharge through) NH3, N2H2 or N3H.

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