Nernst Equation for Cell EMF, Electrochemistry Assignment Help

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Nernst's equation for cell EMF

For a cell in which the net cell reaction involving n electrons is, 1676_nernst equation for cell emf.png

The Nernst equation is written as,

2019_nernst equation for cell emf1.png

Where, 1232_nernst equation for cell emf2.png.

 The Eocell is called the standard cell potential.

or 679_nernst equation for cell emf3.png

At 298 K, above eq. can be written as,

or 32_nernst equation for cell emf4.png         

It may be noted here, that concentrations of D, C, B and A referred in the equations are the concentrations at the time the cell emf is measured. 

 

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