Limitations of valence bond theory
The valence bond theory was fairly successful in explaining qualitatively the geometry and magnetic behaviour of the complexes. However, it could not explain the following:
(i) Origin of their absorption spectra could not be illustrated.
(ii) Why the different complexes of same metal show different colours.
(iii) The relative stabilities of different complexes could not be illustrated.
(iv) Why certain ligands form high spin, while others low spin complexes.
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