Importance of electron affinity, Chemical Periodicity Assignment Help

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Importance of electron affinity : Certain properties of  the elements are predicted on the basis of values of electron affinity.

 

(i) The elements having high value high values of electron affinity are capable of accepting electron easily. They form the anion and electrovalent compounds. This type of elements is electronegative in nature.

(ii) The elements having high values of electron affinity act as strong oxidising agents, for example, F, CL, Br, O, S etc.

On the basis of the general trend of ionisation potential and electron affinity, the below stated properties can be predicted,

(a) Metallic nature decreases in a period while nonmetallic nature increases. The metallic nature increases in the group while non-metallic nature decreases in the group. The arrow  represents a group and  represents a period.

 

2102_factors affecting electron affinity.png

 

(b) Reducing nature decreases in a period while oxidising nature increases. Reducing nature increases in the group while oxidising nature decreases in the group.

 

307_factors affecting electron affinity1.png

(c) The stability of metal increases while activity of metal decreases in the period and in a group stability decreases while activity increases.

1915_factors affecting electron affinity2.png

   This trend is observed particularly in IA, IIA and IIIA elements.

    (d) The basic nature of the oxides decreases in a period while acidic nature increases. In the group, basic nature increases while the acidic nature decrases.

1363_factors affecting electron affinity3.png

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