Heterolysis bond fission or Heterolytic
(i) In heterolysis, the covalent bond is broken in such a way that one species (i.e., less electronegative) is deprived of its own electron, while the other substance gets both the electrons.
Thus formation of opposite charged particles takes place. In case of organic molecules, if positive charge is present on the carbon then cation is termed as carbocation. If negative charge is present on the carbon then anion is termed as carbanion.
(ii) The segment which favors heterolysis is greater difference of electronegativities between A and B.
(iii) Functionality of the solution in which heterolysis takes place is known as heterolytic mechanism or ionic mechanism.
(iv) The energy needs for heterolysis is usually greater than that for homolysis due to electrostatic forces of attraction between ions.
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