Formation of Crystal and Crystal System Assignment Help

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The Formation of crystal and Crystal systems

         The crystals of substance are obtained by cooling the liquid (or melt) of the solution of that substance. The size of crystal depends upon the rate of cooling. If cooling is carried out very slowly, crystals of large size are attained because the particles (such as ions, atoms or the molecules) get enough time to arrange themselves in the proper positions.

         1222_CRYSTAL SYSTEM4.png

         (If loosing units dissolves as an embryo and if gaining unit grow as a crystals).

         Bravais (in the year 1848) showed from geometrical considerations that there can be 14 different ways only in which similar points can be arranged. Thus, there can be 14 different space lattices only. These 14 types of the lattices are known as the Bravais Lattices. But alternatively Bravais showed that there are seven types of crystal systems only.

Crystal system

Space lattice

Examples

Cubic

A=b=c,

α = β = ϒ= 90o

 

Simple: Lattice points at the eight corners of the unit cells.

Body centered: Points at the eight corners and at the body centred.

Face centered: Points at the eight corners and at the six face centres.

 

 

 

 

Pb, Hg, Ag Au, Cu, ZnS, diamond, KCl,  CsCl, NaCl, Cu2O, CaF2 and alums. etc.

Tetragonal

a = b ≠ c,

α =β = ϒ = 90o

 

 

 

Simple : Points at the eight corners of the unit cell.

1231_CRYSTAL SYSTEM.png

Body centered : Points at the eight corners and at the body centre

SnO2, TiO2

ZnO2, NiSO4

ZrSiO4.PbW O4,  white Sn etc.

Orthorhombic (Rhombic)

a ≠b ≠ c,

α =β = ϒ = 90o

 

 

 

Simple: Points at the eight corners of the unit cell.

End centered: Also called side centered or base centered. Points at the eight corners and at two face centres opposite to each other.

 

 

 

 

Body centered : Points at the eight corners and at the body centre

Face centered: Points at the eight corners and at the six face centres.

 

KNO3, K2SO4

PbCO3, BaSO4, rhombic sulphur, MgSO4.7H2O etc.

Rhombohedral

or   Trigonal

a = b = c,

α =β = ϒ ≠ 90o

 

 

Simple : Points at the eight corners of the unit cell

1540_CRYSTAL SYSTEM5.png

NaNO3, CaSO4, calcite, quartz, As, Sb, Bi etc.

Hexagonal

a = b ≠ c,

α =β = 90o

ϒ = 120o

 

Simple: Points at the twelve corners of the unit cell out lined by thick line.

1957_CRYSTAL SYSTEM1.png

 

 

 

 

 

 

or Points at the twelve corners of the hexagonal prism and at the centres of the two hexagonal faces.

ZnO, PbS, CdS, HgS, graphite, ice, Mg, Zn, Cd etc.

Monoclinic

a ≠ b ≠ c,

α = ϒ= 90o

β ≠ 90o

 

Simple : Points at the eight corners of the unit cell

2153_CRYSTAL SYSTEM2.png

End centered : Point at the eight corners and at two face centres opposite to the each other.

Na2SO4.10H2O

Na2B4O7.10H2O

CaSO4.2H2O monoclinic sulphur etc.

 

 

Triclinic

a ≠ b ≠ c,

α ≠ β ≠  ϒ= 90o

 

 

 

 

Simple : Points at the eight corners of the unit cell.

836_CRYSTAL SYSTEM3.png

CaSO4.5H2O K2Cr2O7, H3BO3

etc.

 

 

 

                 


Table :  Bravais lattices corresponding to different crystal systems

 

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